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The present invention relates to colorant stabilizers. The dye stabilizers according to the present invention are capable of stabilizing the dye when exposed to electromagnetic radiation. A serious problem with dyes is that they tend to fade when exposed to electromagnetic radiation such as sunlight or artificial light. It is believed that most of the coloring of the dyes when exposed to light is due to photodegradation mechanisms. Such degradation mechanisms include oxidation or reduction of dyes depending on the environmental conditions in which the dye is present. Fading of the dye also depends on the substrate on which it is found. Product analysis of stable photo products and intermediates revealed several important photodecomposition regimes. These include electron firing from the dye, reaction with oxygen in the basic or excited singlet state, cleavage of the central carbon-phenyl bonds to form amino substituted benzophenones such as triphenylmethane dyes, reduction to form colorless leukophores, and abstraction of the electron or hydrogen atom intermediates. Various factors such as temperature, humidity, gaseous reactants including O 2 , O 3 , SO 2 and NO 2 and water-soluble, non-volatile photodegradation products have been shown to affect dye fading.
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Photopolymerizable composition containing a photosensitive donor and photoinitiating acceptor.
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- In other applications, the particles of the composition should be very small.
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